Electron Shells

Arrange electrons in shells and link the arrangement to the periodic table.

  • Define and explain Electron Shells in your own words
  • Use key terms such as electron accurately
  • Apply what you have learned to new examples and questions
  • Avoid the common mistakes learners make with this topic

This lesson focuses on Electron Shells: arrange electrons in shells and link the arrangement to the periodic table.

Definition: Electron Shells

Arrange electrons in shells and link the arrangement to the periodic table.

Key ideas

Electrons are arranged in shells

Electrons occupy shells around the nucleus, filling from the innermost shell outwards; the first shell holds up to 2 electrons and the second and third hold up to 8. An atom's electron arrangement decides how it reacts — atoms with full outer shells, like the noble gases, are unreactive. Sodium's arrangement 2,8,1 explains why it loses one electron so readily.

Mass number counts the heavy particles

The mass (nucleon) number is the total of protons plus neutrons, since electrons weigh almost nothing. So number of neutrons = mass number − atomic number: for example, an atom with atomic number 6 and mass number 14 has 14 − 6 = 8 neutrons. This simple subtraction unlocks the full structure of any atom.

Key term — electron: A negatively charged particle found in shells around the nucleus, with negligible mass (about 1/1836 of a proton).

Working out an atom's structure

An atom has atomic number 12 and mass number 24. State the numbers of protons, neutrons and electrons, and give its electron arrangement.

Protons = atomic number = 12. Electrons = protons in a neutral atom = 12. Neutrons = mass number − atomic number = 24 − 12 = 12. Arrange 12 electrons in shells: first shell 2, second shell 8, third shell 2, giving 2,8,2.

Answer: 12 protons, 12 neutrons, 12 electrons; electron arrangement 2,8,2 (magnesium).

Common mistakes
  • Putting too many electrons in the first shell The first shell holds a maximum of 2 electrons — it can never hold 8. The pattern is 2 in the first shell, then up to 8 in the second and third.
  • Mixing up atomic number and mass number The atomic number counts protons only; the mass number counts protons plus neutrons. Remember: neutrons = mass number − atomic number, not the other way round.

Practice

Give the electron arrangement of chlorine (atomic number 17).
Fill the shells: 2, then 8, then the rest.

2,8,7.

An atom has 8 protons, 8 neutrons and 8 electrons. Identify the element and give its mass number.
Which element has atomic number 8?

Oxygen; mass number = 8 + 8 = 16.

Explain why an atom has no overall charge.
Compare the numbers of positive and negative particles.

A neutral atom has equal numbers of protons (each +1) and electrons (each −1), so the charges cancel out.

Carbon-12 and carbon-14 are isotopes. State one similarity and one difference between their atoms.
Which particle number never changes in isotopes?

Similarity: both have 6 protons (and 6 electrons), so both are carbon. Difference: carbon-14 has 2 more neutrons, so it is heavier.

Quick check

Electron Shells — quick check

Which of these best defines "electron"?

A negatively charged particle found in shells around the nucleus, with negligible mass (about 1/1836 of a proton).

Explain why the mass of an electron is ignored when calculating mass number.

An electron's relative mass is about 1/1836 of a proton's, which is negligible next to the whole-number masses of protons and neutrons, so it makes no difference to the total.

An ion has 11 protons and 10 electrons. What is its charge?

11 positive charges and 10 negative charges give an overall charge of +1 (a sodium ion).
Key takeaways
  • Electron Shells: arrange electrons in shells and link the arrangement to the periodic table.
  • Electrons are arranged in shells: Electrons occupy shells around the nucleus, filling from the innermost shell outwards; the first shell holds up to 2 electrons and the second and third hold up to 8.
  • proton: A positively charged particle in the nucleus with a relative mass of 1.
  • Watch out for: putting too many electrons in the first shell